@article{Kumar2012Rever-21632,
  year={2012},
  doi={10.1002/ejoc.201200138},
  title={Reversal of Anomeric Selectivity with O-Glycosyl Trichloroacetimidates as Glycosyl Donors and Thiols as Acceptors Under Acid/Base Catalysis},
  number={14},
  volume={2012},
  issn={1434-193X},
  journal={European Journal of Organic Chemistry},
  pages={2715--2719},
  author={Kumar, Amit and Schmidt, Richard R.}
}

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    <dcterms:abstract xml:lang="eng">Boron trifluoride or trimethylsilyl trifluoromethanesulfonate catalysed the generation of thioglycosides from O-glucopyranosyl or O-galactopyranosyl trichloroacetimidates and thiols giving mainly or exclusively α-thioglycosides. However, the same reactions with phenylboron difluoride as catalyst are highly β-selective. An SN2-type reaction course under acid/base catalysis is invoked by these and previous results.</dcterms:abstract>
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