Universität zu Köln

Sahler, Sebastian, Sturm, Sebastian, Kessler, Michael T. and Prechtl, Martin H. G. ORCID: 0000-0003-2155-8006 (2014). The Role of Ionic Liquids in Hydrogen Storage. Chem.-Eur. J., 20 (29). S. 8934 - 8942. WEINHEIM: WILEY-V C H VERLAG GMBH. ISSN 1521-3765

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Abstract

Ionic liquid (IL) based H-2 storage for H-2 generation from NH3BH3 derivatives is shown. These systems promote H-2 generation at low temperature, with good reaction rates and high total H-2 yields. The effects of ILs and the H-2 yield in correlation with the basicity, the cations of the ILs, and the role of carbenes are discussed. Furthermore, mechanistic findings on the dehydrogenation are described. IL material blends are competitive with conventional H-2 storage materials with experimental efficiencies of at least 6.5 wt% H-2.

Item Type:	Journal Article
Creators:	Creators Email ORCID ORCID Put Code Sahler, Sebastian UNSPECIFIED UNSPECIFIED UNSPECIFIED Sturm, Sebastian UNSPECIFIED UNSPECIFIED UNSPECIFIED Kessler, Michael T. UNSPECIFIED UNSPECIFIED UNSPECIFIED Prechtl, Martin H. G. UNSPECIFIED orcid.org/0000-0003-2155-8006 UNSPECIFIED
URN:	urn:nbn:de:hbz:38-433968
DOI:	10.1002/chem.201304868
Journal or Publication Title:	Chem.-Eur. J.
Volume:	20
Number:	29
Page Range:	S. 8934 - 8942
Date:	2014
Publisher:	WILEY-V C H VERLAG GMBH
Place of Publication:	WEINHEIM
ISSN:	1521-3765
Language:	English
Faculty:	Unspecified
Divisions:	Unspecified
Subjects:	no entry
Uncontrolled Keywords:	Keywords Language AMMONIA BORANE; THERMAL-DECOMPOSITION; CATALYTIC-REACTIONS; REGENERATION; DEHYDROGENATION; NANOPARTICLE; COMPLEXES Multiple languages Chemistry, Multidisciplinary Multiple languages
URI:	http://kups.ub.uni-koeln.de/id/eprint/43396